Please use this identifier to cite or link to this item: http://repositorio.unifesp.br/handle/11600/38774
Title: Lewis-acid catalyzed N-acyliminium ion cyclodimerization: synthesis of symmetrical 1,4-dioxanes
Authors: Ali, Bakhat
Zukerman-Schpector, Julio
Ferreira, Fernando P. [UNIFESP]
Shamim, Anwar
Pimenta, Daniel C.
Stefani, Helici A.
Universidade de São Paulo (USP)
Universidade Federal de São Carlos (UFSCar)
Universidade Federal de São Paulo (UNIFESP)
Inst Butantan
Keywords: Amines
N-Acyliminium
Acid catalysis
Cyclodimerization
1,4-Dioxane
Issue Date: 25-Feb-2015
Publisher: Elsevier B.V.
Citation: Tetrahedron Letters. Oxford: Pergamon-Elsevier B.V., v. 56, n. 9, p. 1153-1158, 2015.
Abstract: The cyclodimerization reaction of N-substituted-5-hydroxy-pyrrolydinones promoted by BF3 center dot Et2O and HCl to obtain symmetrical 1,4-dioxane derivatives was achieved in moderate to good yields, mild conditions, and short reaction times. These transformations render a promising alternative route that provides access to diverse 1,4-dioxane derivatives with a wide structural diversity. (C) 2015 Elsevier B.V. All rights reserved.
URI: http://repositorio.unifesp.br/handle/11600/38774
ISSN: 0040-4039
Other Identifiers: http://dx.doi.org/10.1016/j.tetlet.2015.01.059
Appears in Collections:Em verificação - Geral

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