Please use this identifier to cite or link to this item: http://repositorio.unifesp.br/handle/11600/34074
Title: (R)-2-Phenoxy-1-(4-phenyl-2-sulfanylidene-1,3-oxazolidin-3-yl)ethanone
Authors: Caracelli, Ignez
Coelho, Daniel C. S.
Olivato, Paulo R.
Correra, Thiago C.
Rodrigues, Alessandro [UNIFESP]
Tiekink, Edward R. T.
Universidade Federal de São Carlos (UFSCar)
Universidade de São Paulo (USP)
Universidade Federal de São Paulo (UNIFESP)
Univ Malaya
Issue Date: 1-Oct-2011
Publisher: Wiley-Blackwell
Citation: Acta Crystallographica Section E-structure Reports Online. Hoboken: Wiley-Blackwell, v. 67, p. O2755-+, 2011.
Abstract: The central 1,3-oxazolidine-2-thione ring in the title compound, C17H15NO3S, is approximately planar with maximum deviations of 0.036 (4) and -0.041 (5) angstrom for the O and methylene-C atoms, respectively. the dihedral angles formed between this plane and the two benzene rings, which lie to the same side of the central plane, are 86.5 (2) [ring-bound benzene] and 50.6 (3)degrees. the ethan-1-one residue is also twisted out of the central plane, forming a O-C-N-C torsion angle of 151.5 (5)degrees. the dihedral angle formed by the benzene rings is 62.8 (2)degrees so that overall, the molecule has a twisted U-shape. in the crystal, molecules are linked into supramolecular arrays two molecules thick in the bc plane through C-H center dot center dot center dot O, C-H center dot center dot center dot S and C-H center dot center dot center dot pi interactions.
URI: http://repositorio.unifesp.br/handle/11600/34074
ISSN: 1600-5368
Other Identifiers: http://dx.doi.org/10.1107/S160053681103858X
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