Synthesis of Lapachone Derivates via Ionic Liquid-Mediated Tandem Knoevenagel/Diels-Alder Reaction

Synthesis of Lapachone Derivates via Ionic Liquid-Mediated Tandem Knoevenagel/Diels-Alder Reaction

Author Prado, Karinne E. Google Scholar
Name, Luccas L. Google Scholar
Oliveira, Rayssa P. Google Scholar
Guadagnin, Rafael C. Autor UNIFESP Google Scholar
Pimenta, Daniel C. Google Scholar
Pena, Jesus M. Google Scholar
Cella, Rodrigo Google Scholar
Abstract The use of ionic liquid (IL) in Tandem Knoevenagel/Diels-Alder Reaction is an optimization method for one-pot procedures, providing great results under mild conditions. In this paper, four new Lapachone derivatives were obtained using lawsone as substrate. The effects of the catalytic use of ionic liquids and catalysts in organometallic systems were evaluated. Several lapachone derivatives were obtained good to excellent yields.
Keywords Diels/Alder
ionic liquid
Koevenagel
lapachone
quinone
Language English
Sponsor Brazilian agency National Council for Scientific and Technological Development, CNPq
FINEP
Grant number CNPq: 473136/2013-9
FINEP: 01.09.0278.04
Date 2017
Published in Chemistryselect. Weinheim, v. 2, n. 24, p. 7421-7425, 2017.
ISSN 2365-6549 (Sherpa/Romeo, impact factor)
Publisher Wiley-V C H Verlag Gmbh
Extent 7421-7425
Origin http://dx.doi.org/10.1002/slct.201701861
Access rights Closed access
Type Article
Web of Science ID WOS:000408644100069
URI http://repositorio.unifesp.br/handle/11600/51378

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