(R)-2-Phenoxy-1-(4-phenyl-2-sulfanylidene-1,3-oxazolidin-3-yl)ethanone

(R)-2-Phenoxy-1-(4-phenyl-2-sulfanylidene-1,3-oxazolidin-3-yl)ethanone

Author Caracelli, Ignez Google Scholar
Coelho, Daniel C. S. Google Scholar
Olivato, Paulo R. Google Scholar
Correra, Thiago C. Google Scholar
Rodrigues, Alessandro Autor UNIFESP Google Scholar
Tiekink, Edward R. T. Google Scholar
Institution Universidade Federal de São Carlos (UFSCar)
Universidade de São Paulo (USP)
Universidade Federal de São Paulo (UNIFESP)
Univ Malaya
Abstract The central 1,3-oxazolidine-2-thione ring in the title compound, C17H15NO3S, is approximately planar with maximum deviations of 0.036 (4) and -0.041 (5) angstrom for the O and methylene-C atoms, respectively. the dihedral angles formed between this plane and the two benzene rings, which lie to the same side of the central plane, are 86.5 (2) [ring-bound benzene] and 50.6 (3)degrees. the ethan-1-one residue is also twisted out of the central plane, forming a O-C-N-C torsion angle of 151.5 (5)degrees. the dihedral angle formed by the benzene rings is 62.8 (2)degrees so that overall, the molecule has a twisted U-shape. in the crystal, molecules are linked into supramolecular arrays two molecules thick in the bc plane through C-H center dot center dot center dot O, C-H center dot center dot center dot S and C-H center dot center dot center dot pi interactions.
Language English
Sponsor Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
Grant number CAPES: 808/2009
Date 2011-10-01
Published in Acta Crystallographica Section E-structure Reports Online. Hoboken: Wiley-Blackwell, v. 67, p. O2755-+, 2011.
ISSN 1600-5368 (Sherpa/Romeo, impact factor)
Publisher Wiley-Blackwell
Extent O2755-+
Origin http://dx.doi.org/10.1107/S160053681103858X
Access rights Open access Open Access
Type Article
Web of Science ID WOS:000295615400123
URI http://repositorio.unifesp.br/handle/11600/34074

Show full item record




File

Name: WOS000295615400123.pdf
Size: 644.0Kb
Format: PDF
Description:
Open file

This item appears in the following Collection(s)

Search


Browse

Statistics

My Account